Welcome to Smogon! Take a moment to read the Introduction to Smogon for a run-down on everything Smogon, and make sure you take some time to read the global rules.
When are you free? I am GMT -4 now so that helps a little. I can play Tuesday between 9-12am or anytime after 4pm my time wednesday i can play between 1:30-4 or anytime after 6pm my time.